Difference between sigma bond and pi bond (Sigma bond vs Pi bond) The process of mixing of atomic orbitals of nearly same energy to produce a set of entirely new orbitals of equivalent energy (hybrid orbitals) is known as hybridization. Atomic orbitals of almost the same energy belonging to the same atom or ion can take part in hybridization.. The number of hybrid orbitals formed is always equal to the number of atomic orbitals taking part in hybridization. The hybrid orbitals repel each other and tend to be farthest apart. Hybrid orbitals forms only sigma (σ bonds ) σ and pi bonds( π bonds ) are formed by unhybridised orbitals. Sigma bond : This type of covalent bond is formed by the axial or end to end overlapping of half filled atomic orbitals of the atoms participating in bonding. The electron cloud formed as a result of axial overlap is cylindrically symmetrical about inter nuclear axis. Pi bond : This type of bond is formed by lateral or side wise overlap